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  7. Chloromethyl methyl sulfide, 94%, Thermo Scientific Chemicals

Chloromethyl methyl sulfide, 94%, Thermo Scientific Chemicals

Product Code. 11393036
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Quantity:
10 g
50 g
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This item is not returnable. View return policy

Description

Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

Solubility
Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 2373-51-5
Molecular Formula C2H5ClS
Molecular Weight (g/mol) 96.57
MDL Number MFCD00000923
InChI Key JWMLCCRPDOIBAV-UHFFFAOYSA-N
Synonym chloromethyl methyl sulfide, chlorodimethyl sulfide, methylthiomethyl chloride, chloro methylthio methane, methane, chloro methylthio, chlorodimethyl thioether, chloromethyl methyl thioether, monochlorodimethyl sulfide, chloro methylsulfanyl methane, clorodimetilsolfuro
PubChem CID 16916
IUPAC Name chloro(methylsulfanyl)methane
SMILES CSCCl

Specifications

Density 1.16
Boiling Point 104°C to 105°C
Flash Point 17°C (62°F)
Odor Stench
Refractive Index 1.498
Quantity 50 g
UN Number UN1993
Beilstein 1730851
Sensitivity Moisture sensitive
Solubility Information Soluble in acetonitrile,ether and dichloromethane. Insoluble in water.
Formula Weight 96.58
Percent Purity 95%
Chemical Name or Material Chloromethyl methyl sulfide
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