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1,3-Bis(diphenylphosphino)propane, 97%, Thermo Scientific Chemicals Product Code.: 11439763
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1,3-Bis(diphenylphosphino)propane, 97%, Thermo Scientific Chemicals

Product Code. 11439763
100 g
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5 g
25 g
100 g
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Product Code. 11439763

Brand: Thermo Scientific Alfa Aesar A12931.22

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Description

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Solubility
Insoluble in water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 6737-42-4
Molecular Formula C27H26P2
Molecular Weight (g/mol) 412.45
MDL Number MFCD00003050
InChI Key LVEYOSJUKRVCCF-UHFFFAOYSA-N
Synonym 1,3-bis diphenylphosphino propane, dppp, trimethylenebis diphenylphosphine, phosphine, 1,3-propanediylbis diphenyl, 3-diphenylphosphanyl propyl diphenylphosphane, 3-diphenylphosphanylpropyl diphenyl phosphane, 1,3-bis diphenyphosphino propane, 1,3-bis diphenylphosphino propane dppp, bis 1,3-diphenylphosphino propane, 1,3-bis-diphenylphosphino propane
PubChem CID 81219
IUPAC Name 3-diphenylphosphanylpropyl(diphenyl)phosphane
SMILES C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 58°C to 63°C
Linear Formula (C6H5)2P(CH2)3P(C6H5)2
Quantity 100 g
Beilstein 2821785
Sensitivity Air Sensitive
Solubility Information Insoluble in water.
Formula Weight 412.46
Percent Purity 97%
Chemical Name or Material 1,3-Bis(diphenylphosphino)propane

RUO – Research Use Only

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