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Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals
2490.00 SEK - 8795.00 SEK
Chemical Identifiers
CAS | 212713-08-1 |
---|---|
Molecular Formula | C30H46ClO2P |
Molecular Weight (g/mol) | 505.12 |
MDL Number | MFCD08458881 |
InChI Key | VOGHMZHRQUWLRE-UHFFFAOYSA-N |
Synonym | bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ciShow More |
PubChem CID | 53431072 |
IUPAC Name | chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane |
SMILES | CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)Cl |
Description
It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIt is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.
Solubility
Reacts with water.
Notes
Air & moisture sensitive. Materials to avoid is oxidizing agents, bases.
Chemical Identifiers
212713-08-1 | |
505.12 | |
VOGHMZHRQUWLRE-UHFFFAOYSA-N | |
53431072 | |
CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)ClShow More |
C30H46ClO2P | |
MFCD08458881 | |
bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ciShow More | |
chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane |
Specifications
212713-08-1 | |
MFCD08458881 | |
Air and moisture sensitive | |
Reacts with water. | |
CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)Cl | |
505.12 | |
505.13 | |
Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine |
C30H46ClO2P | |
UN3261 | |
bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ci | |
VOGHMZHRQUWLRE-UHFFFAOYSA-N | |
chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane | |
53431072 | |
94% |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H335
missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
missing translation for 'einecsNumber' : 000-000-0
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only
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