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Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals

2490.00 SEK - 8795.00 SEK

Chemical Identifiers

CAS	212713-08-1
Molecular Formula	C30H46ClO2P
Molecular Weight (g/mol)	505.12
MDL Number	MFCD08458881
InChI Key	VOGHMZHRQUWLRE-UHFFFAOYSA-N
Synonym	bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ciShow More Show Less
PubChem CID	53431072
IUPAC Name	chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
SMILES	CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)Cl

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Products 2

Product Code	Brand	Quantity	Price	Quantity & Availability
Product Code	Brand	Quantity	Price	Quantity & Availability
11475620 SDS View Documents missing translation for 'viewProductCertificates'	Thermo Scientific Alfa Aesar H25882.03	1 g	This item is currently unavailable or has been discontinued. View the product page for possible alternatives.		N/A

11485620 SDS View Documents missing translation for 'viewProductCertificates'	Thermo Scientific Alfa Aesar H25882.06	5 g	This item is currently unavailable or has been discontinued. View the product page for possible alternatives.		N/A

Description

It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Materials to avoid is oxidizing agents, bases.

Specifications

Chemical Identifiers

CAS	212713-08-1
Molecular Weight (g/mol)	505.12
InChI Key	VOGHMZHRQUWLRE-UHFFFAOYSA-N
PubChem CID	53431072
SMILES	CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)ClShow More Show Less

Molecular Formula	C30H46ClO2P
MDL Number	MFCD08458881
Synonym	bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ciShow More Show Less
IUPAC Name	chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane

Specifications

CAS	212713-08-1
MDL Number	MFCD08458881
Sensitivity	Air and moisture sensitive
Solubility Information	Reacts with water.
SMILES	CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)Cl
Molecular Weight (g/mol)	505.12
Formula Weight	505.13
Chemical Name or Material	Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine

Molecular Formula	C30H46ClO2P
UN Number	UN3261
Synonym	bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ci
InChI Key	VOGHMZHRQUWLRE-UHFFFAOYSA-N
IUPAC Name	chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
PubChem CID	53431072
Percent Purity	94%

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

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missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

RUO – Research Use Only

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Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals

Chemical Identifiers

Description

Chemical Identifiers

Specifications

Safety and Handling

Documents