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  8. Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals

Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals

2490.00 SEK - 8795.00 SEK

Chemical Identifiers

CAS 212713-08-1
Molecular Formula C30H46ClO2P
Molecular Weight (g/mol) 505.12
MDL Number MFCD08458881
InChI Key VOGHMZHRQUWLRE-UHFFFAOYSA-N
Synonym bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ci
PubChem CID 53431072
IUPAC Name chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
SMILES CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)Cl
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11475620
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Thermo Scientific Alfa Aesar
H25882.03 		1 g This item is currently unavailable or has been discontinued.
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11485620
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Thermo Scientific Alfa Aesar
H25882.06 		5 g This item is currently unavailable or has been discontinued.
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Description

Description

It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Materials to avoid is oxidizing agents, bases.
Specifications
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Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

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Recommended Storage : Ambient temperatures; Store under Nitrogen

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