missing translation for 'onlineSavingsMsg'
Learn More

Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals

2490.00 SEK - 8795.00 SEK

Chemical Identifiers

CAS 212713-08-1
Molecular Formula C30H46ClO2P
Molecular Weight (g/mol) 505.12
MDL Number MFCD08458881
InChI Key VOGHMZHRQUWLRE-UHFFFAOYSA-N
Synonym bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ciShow MoreShow Less
PubChem CID 53431072
IUPAC Name chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
SMILES CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)Cl
View More Specs

Products 2
Product Code Brand Quantity Price Quantity & Availability  
Product Code Brand Quantity Price Quantity & Availability  
11475620
SDS View Documents
Thermo Scientific Alfa Aesar
H25882.03
1 g This item is currently unavailable or has been discontinued.
View the product page for possible alternatives.
N/A
11485620
SDS View Documents
Thermo Scientific Alfa Aesar
H25882.06
5 g This item is currently unavailable or has been discontinued.
View the product page for possible alternatives.
N/A
Description

Description

It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Materials to avoid is oxidizing agents, bases.
Specifications
Show More
Videos
Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.

missing translation for 'einecsNumber' : 000-000-0

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only

Product Content Correction

Your input is important to us. Please complete this form to provide feedback related to the content on this product.

Product Title
Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.

Thank You! Your feedback has been submitted. Fisher Scientific is always working to improve our content for you. We appreciate your feedback.