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Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%, Thermo Scientific Chemicals
Coupling reactions, Suzuki couplings
Chemical Identifiers
CAS | 95408-45-0 |
---|---|
Molecular Formula | C26H44Cl2FeP2Pd |
Molecular Weight (g/mol) | 651.75 |
MDL Number | MFCD08064219 |
InChI Key | DFRHTHSZMBROSH-UHFFFAOYSA-N |
Synonym | [1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) dichloride; PdCl2(dtbpf) |
IUPAC Name | Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II) |
SMILES | [Fe].Cl[Pd]Cl.CC(C)(C)P(c1cccc1)C(C)(C)C.CC(C)(C)P(c1cccc1)C(C)(C)C |
Description
Coupling reactions, Suzuki couplings.Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
- Packaged under Argon
Chemical Identifiers
95408-45-0 | |
651.75 | |
DFRHTHSZMBROSH-UHFFFAOYSA-N | |
Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II) |
C26H44Cl2FeP2Pd | |
MFCD08064219 | |
[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) dichloride; PdCl2(dtbpf) | |
[Fe].Cl[Pd]Cl.CC(C)(C)P(c1cccc1)C(C)(C)C.CC(C)(C)P(c1cccc1)C(C)(C)C |
Specifications
95408-45-0 | |
C26H44Cl2FeP2Pd | |
[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) dichloride; PdCl2(dtbpf) | |
DFRHTHSZMBROSH-UHFFFAOYSA-N | |
Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II) | |
651.77 | |
Crystalline |
Red | |
MFCD08064219 | |
Soluble in dichloromethane and chloroform. Partially soluble in acetone,alcohols,tertrahydrofuran and dioxane. | |
[Fe].Cl[Pd]Cl.CC(C)(C)P(c1cccc1)C(C)(C)C.CC(C)(C)P(c1cccc1)C(C)(C)C | |
651.75 | |
Pd 16.3% | |
Dichloro[1,1'-bis (di-tert-butylphosphino)ferrocene]palladium (II) |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
H302+H312+H332-H315-H319
missing translation for 'tsca' : No
missing translation for 'storageNote' :
- Packaged under Argon
Recommended Storage : Ambient temperatures; Store under Argon
RUO – Research Use Only