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  8. Ethyl glyoxylate, ca 50% soln. in toluene, Thermo Scientific Chemicals

Ethyl glyoxylate, ca 50% soln. in toluene, Thermo Scientific Chemicals

Product Code. 11344076
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Quantity:
100 g
500 g

Description

Ethyl glyoxylate is widely used as an intermediate in the synthesis of pharmaceuticals (high reactivity of aldehyde function). It is used in the synthesis of a biodegradable polymer, poly(ethyl glyoxylate). It is actively involved in the Friedel-Crafts alkylation reactions with thiophenes to give the corresponding secondary alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethyl glyoxylate is widely used as an intermediate in the synthesis of pharmaceuticals (high reactivity of aldehyde function). It is used in the synthesis of a biodegradable polymer, poly(ethyl glyoxylate). It is actively involved in the Friedel-Crafts alkylation reactions with thiophenes to give the corresponding secondary alcohols.

Solubility
Immiscible with water.

Notes
Air sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 924-44-7
Molecular Formula C4H6O3
Molecular Weight (g/mol) 102.089
MDL Number MFCD00044009
InChI Key DBPFRRFGLYGEJI-UHFFFAOYSA-N
Synonym ethyl glyoxalate, ethyl glyoxylate, ethyl oxoacetate, glyoxylic acid ethyl ester, acetic acid, oxo-, ethyl ester, ethyl glyoxalate solution, unii-ixx9mq1j1i, acetic acid, 2-oxo-, ethyl ester, ixx9mq1j1i, 2-oxoacetic acid, ethyl ester
PubChem CID 70211
ChEBI CHEBI:53275
IUPAC Name ethyl 2-oxoacetate
SMILES CCOC(=O)C=O

Specifications

Density 1.003
Boiling Point 110°C
Flash Point 7°C (44°F)
Refractive Index 1.475
Quantity 100 g
UN Number UN1993
Beilstein 1209486
Sensitivity Air Sensitive
Solubility Information Immiscible with water.
Formula Weight 102.09
Concentration or Composition (by Analyte or Components) ≈50% soln. in toluene
Chemical Name or Material Ethyl glyoxylate
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Safety and Handling

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Product Identifier
  • Ethyl glyoxylate, ca 50% solution in toluene
 Signal Word
  • Danger
 Hazard Category
  • Aspiration toxicity Category 1
  • Flammable liquid Category 2
  • Reproductive toxicity Category 2
  • Skin corrosion/irritation Category 2
  • Skin sensitiser Category 1
  • Specific target organ toxicity after repeated exposure Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H225-Highly flammable liquid and vapour.
  • H304-May be fatal if swallowed and enters airways.
  • H315-Causes skin irritation.
  • H317-May cause an allergic skin reaction.
  • H336-May cause drowsiness or dizziness.
  • H361d-Suspected of damaging the unborn child.
  • H373-May cause damage to organs.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P240-Ground/bond container and receiving equipment.
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
 Supplemental information
  • MIXTURE LIST-Contains : toluene, oxo-aceticacid

RUO – Research Use Only

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