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  5. Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™, Thermo Scientific Chemicals

Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™, Thermo Scientific Chemicals

Product Code. 10174680
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Quantity:
100 mL
800 mL
Packaging:
AcroSeal™ Glass bottle
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Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.
This item is not returnable. View return policy
Request Bulk Custom & GMP Chemicals
Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 4111-54-0, 142-82-5, 109-99-9, 100-41-4, 108-18-9
Molecular Formula C6H14LiN
Molecular Weight (g/mol) 107.125
MDL Number MFCD00064449
InChI Key ZCSHNCUQKCANBX-UHFFFAOYSA-N
Synonym lithium diisopropylamide, unii-ol028kiw1i, lithium di-isopropylamide, lithium diisopropyl amide, 2-propanamine, n-1-methylethyl-, lithium salt, ol028kiw1i, lithium di propan-2-yl azanide, 2-propanamine, n-1-methylethyl-, lithium salt 1:1, lithium n,n-diisopropylamide, ipr2nli
PubChem CID 2724682
IUPAC Name lithium;di(propan-2-yl)azanide
SMILES [Li+].CC(C)[N-]C(C)C

Specifications

Color Brown-Red or Orange to Yellow
Boiling Point 60.0°C to 136.0°C
Composition Solvent: THF 59%, n-Heptane: 28%, Ethylbenzene: 13%
Concentration Lithium diisopropylamide: 26.0% (2.0M)
Fieser 02,49; 03,184; 04,298; 05,400; 06,334; 07,204; 08,292; 09,280; 10,241; 11,296; 12,277; 14,193; 15,188; 16,15; 17,165
Density 0.8100g/mL
Merck Index 15, 3215
Solubility Information Solubility in water: decomposes. Other solubilities: soluble in thf, n-heptane, ethylbenzene, miscible with liquid aliphatic and aromatic, hydrocarbons, ethers and tertiary amines
Formula Weight 107.12
Percent Purity 24.6 to 30.0% (Lithium diisopropylamide)
Packaging AcroSeal™ Glass bottle
Specific Gravity 0.81
Quantity 100 mL
Flash Point 2°C
Physical Form Solution
Chemical Name or Material Lithium diisopropylamide, 2M Solution in THF/n-Heptane
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Safety and Handling

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Product Identifier
  • Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 4
  • LONG-TERM AQUATIC HAZARD Chronic 2
  • Aspiration toxicity Category 1
  • Carcinogenicity Category 2
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 2
  • Skin corrosion/irritation Category 1 B
  • Specific target organ toxicity after repeated exposure Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H304-May be fatal if swallowed and enters airways.
  • H318-Causes serious eye damage.
  • H314-Causes severe skin burns and eye damage.
  • H351-Suspected of causing cancer.
  • H373-May cause damage to organs.
  • H411-Toxic to aquatic life with long lasting effects.
  • H335-May cause respiratory irritation.
  • H336-May cause drowsiness or dizziness.
  • H302-Harmful if swallowed.
  • H225-Highly flammable liquid and vapour.
  • EUH014-Reacts violently with water.
  • EUH019-May form explosive peroxides.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only

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